Wednesday, April 10, 2013

Q 10 Calculate the efficiency of packing in case of a metal crystal for (i) simple cubic (ii) body–centred cubic (iii) face–centred cubic (with the assumptions that atoms are touching each other).

Q 10 Calculate the efficiency of packing in case of a metal crystal for
(i) simple cubic
(ii) body–centred cubic
(iii) face–centred cubic (with the assumptions that atoms are touching each other).
(i)
In a simple cubic lattice the atoms are located only on the corners of the cube.
Let take edge length or side of the cube = a,
Let take radius of each particles               = r
The relation between radius and edge a
                 a     = 2r
The volume of the cubic unit cell             = side3
                                                                     = a3
                                                                     = (2r)3
                                                                     = 8r3
Number of atoms in unit cell  = 8 x 1 /8
                                                   = 1
The volume of the occupied space = (4/3)πr3
 

(ii) In body centered cubic two atoms diagonally


Let take edge length or side of the cube = a,
Let take radius of each particles               = r
The diagonal of a cube is always a√3
The relation between radius and edge a will
 a√3 = 4r
divide by root 3 we get
                        a          = 4r/√3
total number of atoms in body centered cubic
number of atoms at the corner = 8 x 1/8 = 1
number of atoms at the center = 1
total number of atoms               = 2
The volume of the cubic unit cell    = side3
                                                            = a3
                                                            = (4r/√3)3
The volume of the occupied space = (4/3)πr3
.

(iii)
Let take edge length or side of the cube = a,
Let take radius of each particles               = r

The diagonal of a square  is always a√2
The relation between radius and edge a will
 a√2 = 4r
divide by root 3 we get
                        a          = 4r/√2
total number of atoms in body centered cubic
number of atoms at the corner = 8 x 1/8 = 1
number of atoms at the face    = 6 x1/2    = 3
total number of atoms                                 = 4
The volume of the cubic unit cell             = side3
                                                                       = a3
                                                                       = (4r/√2)3
                                                                        = (2√2 r)3

The volume of the occupied space = (4/3)πr3
.

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